A convenient one pot synthesis, crystal structure and chemiluminescence of S,S-diphenyl ethanebis(thioate) compound
نویسندگان
چکیده
ABSTRACT. A compound S,S-bis(2-(prop-1-yn-1-yl)phenyl) ethanebis(thioate) is synthesized through one-pot synthesis. The lithiation reaction of 3-bromo-2-methylbenzo[b]thiophene by using n-butyllithium, followed conversion to the corresponding organocopper compound, and subsequent with oxalyl chloride afford target compound. chemical structure final well confirmed NMR, HRMS X-ray analysis. Meanwhile, proposed mechanism fully discussed. Furthermore, chemiluminescent release light also investigated. This work provides a convenient synthetic approach for obtaining S,S-diphenyl broadening its application in chemiluminescence.
 
 KEY WORDS: One pot synthesis, S,S-Diphenyl Crystal structure, Reaction mechanism, Chemiluminescence
 Bull. Chem. Soc. Ethiop. 2023, 37(5), 1185-1191. DOI: https://dx.doi.org/10.4314/bcse.v37i5.11
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ژورنال
عنوان ژورنال: Bulletin of The Chemical Society of Ethiopia
سال: 2023
ISSN: ['1011-3924', '1726-801X']
DOI: https://doi.org/10.4314/bcse.v37i5.11